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Public opinion surveys constitute a widespread, powerful tool to study peoples’ attitudes and behaviors from comparative perspectives. However, even global surveys can have limited geographic and temporal coverage, which can hinder the production of comprehensive knowledge. To expand the scope of comparison, social scientists turn to ex-post harmonization of variables from datasets that cover similar topics but in different populations and/or at different times. These harmonized datasets can be analyzed as a single source and accessed through various data portals. However, the Survey Data Recycling (SDR) research project has identified three challenges faced by social scientists when using data portals: the lack of capability to explore data in-depth or query data based on customized needs, the difficulty in efficiently identifying related data for studies, and the incapability to evaluate theoretical models using sliced data. To address these issues, the SDR research project has developed the SDR Querier, which is applied to the harmonized SDR database. The SDR Querier includes a BERT-based model that allows for customized data queries through research questions or keywords (Query-by-Question), a visual design that helps users determine the availability of harmonized data for a given research question (Query-by-Condition), and the ability to reveal the underlying relational patterns among substantive and methodological variables in the database (Query-by-Relation), aiding in the rigorous evaluation or improvement of regression models. Case studies with multiple social scientists have demonstrated the usefulness and effectiveness of the SDR Querier in addressing daily challenges. 

Abstract Recently, electrical discharges have been identified as a potentially significant source of the atmosphere's most important oxidant, the hydroxyl radical. Measurements of hydroxyl, the closely related hydroperoxyl radical, and the nitrogen oxides from sparks and subvisible discharges were made in the laboratory under different environmental and electrical conditions representing those found in the troposphere. However, there were still several conditions not yet investigated that could impact hydroxyl and hydroperoxyl production in electrical discharges. In this study, the production of electrically generated hydroxyl and hydroperoxyl (LHO_x) and nitrogen oxides (LNO_x) was measured under three new conditions not tested previously, including lower pressure, different temperatures, and the presence of cloud droplet‐sized water droplets. In spark discharges, LHO_xwas mostly independent of pressure, increased with increasing temperature, and was unaffected by the water droplets. LNO_xgeneration was independent of temperature from −10 to 40°C and the presence of water droplets, but increased 1.5‐fold with decreasing pressure. LNO_xgeneration was also found to be sensitive to changes in spark intensity and air flow in the laboratory setup. Increasing temperature also made it more likely that a discharge was visible instead of subvisible, but did not impact LHO_xproduction in subvisible discharges. Even under these new conditions, the laboratory results agree with results of LHO_xfrom a field campaign, demonstrating the relevance of the laboratory experiments to the atmosphere. 

Conjugated copolymers containing electron donor and acceptor units in their main chain have emerged as promising materials for organic electronic devices due to their tunable optoelectronic properties. Herein, we describe the use of direct arylation polymerization to create a series of fully π-conjugated copolymers containing the highly tailorable purine scaffold as a key design element. To create efficient coupling sites, dihalopurines are flanked by alkylthiophenes to create a monomer that is readily copolymerized with a variety of conjugated comonomers, ranging from electron-donating 3,4-dihydro-2 H -thieno[3,4- b ][1,4]dioxepine to electron-accepting 4,7-bis(5-bromo-3-hexylthiophen-2-yl)benzo[ c ][1,2,5]thiadiazole. The comonomer choice and electronic nature of the purine scaffold allow the photophysical properties of the purine-containing copolymers to be widely varied, with optical bandgaps ranging from 1.96–2.46 eV, and photoluminescent quantum yields as high as ϕ = 0.61. Frontier orbital energy levels determined for the various copolymers using density functional theory tight binding calculations track with experimental results, and the geometric structures of the alkylthiophene-flanked purine monomer and its copolymer are found to be nearly planar. The utility of direct arylation polymerization and intrinsic tailorability of the purine scaffold highlight the potential of these fully conjugated polymers to establish structure–property relationships based on connectivity pattern and comonomer type, which may broadly inform efforts to advance purine-containing conjugated copolymers for various applications. 

The SDR Database v.2.0 (SDR2) is a multi-country, multi-year database for research on political participation, social capital, and well-being. It comprises harmonized information from 23 international survey projects, covering over 4.4 million respondents from 156 countries in the period 1966 – 2017. SDR2 provides both target variables and methodological indicators that store source survey and ex-post harmonization metadata. SDR2 consists of three datasets. The MASTER file, which stores harmonized information for a total of 4,402,489 respondents. The auxiliary PLUG-SURVEY file containing controls for source data quality and a set of technical variables needed for merging this file with the MASTER file. And the PLUG-COUNTRY file, which is a dictionary of countries and territories used in the MASTER file. An overall description of the SDR2 Database, and detailed information about its datasets are available in the SDR2 documentation. SDR2 is a product of the project Survey Data Recycling: New Analytic Framework, Integrated Database, and Tools for Cross-national Social, Behavioral and Economic Research, financed by the US National Science Foundation (PTE Federal award 1738502). We thank the Ohio State University and the Institute of Philosophy and Sociology, Polish Academy of Sciences, for organizational support. 

This special issue examines innovative methods in three areas of protest studies: (1) survey methodology and scaling, (2) the development and assessment of political event data, and (3) methods of contextual analysis. The articles provide new techniques and general methodologies for improving the quality of data that we have about protest, especially in the comparative study of protest. 

The sub-Jovian desert is a region in the mass-period and radius-period parameter space that typically encompasses short-period ranges between super-Earths and hot Jupiters, and exhibits an intrinsic dearth of planets. This scarcity is likely shaped by photoevaporation caused by the stellar irradiation received by giant planets that have migrated inward. We report the detection and characterization of TOI-3568 b, a transiting super-Neptune with a mass of 26.4 ± 1.0 M_⊕, a radius of 5.30 ± 0.27 R_⊕, a bulk density of 0.98 ± 0.15 g cm⁻³, and an orbital period of 4.417965 (5) d situated in the vicinity of the sub-Jovian desert. This planet orbiting a K dwarf star with solar metallicity was identified photometrically by the Transiting Exoplanet Survey Satellite (TESS). It was characterized as a planet by our high-precision radial-velocity (RV) monitoring program using MAROON-X at Gemini North, supplemented with additional observations from the SPICE large program with SPIRou at CFHT. We performed a Bayesian MCMC joint analysis of the TESS and ground-based photometry, and MAROON-X and SPIRou RVs, to measure the orbit, radius, and mass of the planet, as well as a detailed analysis of the high-resolution flux and polarimetric spectra to determine the physical parameters and elemental abundances of the host star. Our results reveal TOI-3568 b to be a hot super-Neptune rich in hydrogen and helium, with a core of heavier elements of between 10 and 25 M_⊕in mass. We analyzed the photoevaporation status of TOI-3568 b and find that it experiences one of the highest extreme-ultraviolet (EUV) luminosities among planets with a mass of M_p< 2 M_Nep, yet it has an evaporation lifetime exceeding 5 Gyr. Positioned in the transition between two significant populations of exoplanets on the mass-period and energy diagrams, this planet presents an opportunity to test theories concerning the origin of the sub-Jovian desert. 

A common claim about the affluent democracies is that protest is trending, becoming more legitimate and widely used by all political contenders. In the new democracies, protest is seen as having contributed to democratization, but growing apathy has led to protest decline while in authoritarian regimes protest may be spurring more democratization. Assessing these ideas requires comparative trend data covering 15 or more years but constructing such data confronts problems. The major problem is that the most available survey item asks “have you ever joined (lawful) demonstrations,” making it difficult to time when this protest behavior occurred. We advance a novel method for timing these “ever” responses by focusing on young adults (aged 18-23 years), who are likely reporting on participation within the past 5 years. Drawing on the Survey Data Recycling harmonized data set, we use a multilevel model including harmonization and survey quality controls to create predicted probabilities for young adult participation (576 surveys, 119 countries, 1966-2010). Aggregating these to create country-year rate estimates, these compare favorably with overlapping estimates from surveys asking about “the past 5 years or so” and event data from the PolDem project. Harmonization and survey quality controls improve these predicted values. These data provide 15+ years trend estimates for 60 countries, which we use to illustrate the possibilities of estimating comparative protest trends. 

Context.Small planets transiting bright nearby stars are essential to our understanding of the formation and evolution of exoplanetary systems. However, few constitute prime targets for atmospheric characterization, and even fewer are part of multiple star systems. Aims.This work aims to validate TOI-4336 A b, a sub-Neptune-sized exoplanet candidate identified by the TESS space-based transit survey around a nearby M dwarf. Methods.We validated the planetary nature of TOI-4336 A b through the global analysis of TESS and follow-up multi-band high-precision photometric data from ground-based telescopes, medium- and high-resolution spectroscopy of the host star, high-resolution speckle imaging, and archival images. Results.The newly discovered exoplanet TOI-4336 A b has a radius of 2.1 ± 0.1R_⊕. Its host star is an M3.5-dwarf star with a mass of 0.33 ± 0.01M_⊙and a radius of 0.33 ± 0.02R_⊙, and is a member of a hierarchical triple M-dwarf system 22 pc away from the Sun. The planet’s orbital period of 16.3 days places it at the inner edge of the habitable zone of its host star, which is the brightest of the inner binary pair. The parameters of the system make TOI-4336 A b an extremely promising target for the detailed atmospheric characterization of a temperate sub-Neptune by transit transmission spectroscopy with JWST.